The history of the periodic table and how it hinted at atoms possessing internal structure

By organizing elements by atomic weight, Dmitri Mendeleev created the periodic table

The organization included groupings based on similar chemical properties and patterns in atomic weights. This left gaps that were used to predict the properties of elements yet to be discovered—including germanium and gallium—with high accuracy.

The periodic table organizes elements by atomic structure and common properties

Developed by Dmitri Mendeleev in 1869, the arrangement places elements into columns, called groups, if they share the same number of electrons in their outer shell, indicating similar chemical behavior. From left to right across rows, or periods, elements have more protons, as well as corresponding electrons when neutral.

Besides the periodic table, there are over 1,000 alternative ways to organize the known elements, with many arrangements emphasizing specific trends among them.

Explore an interactive periodic table of each element's history, properties, and uses.

View the evolution of atomic models, with four successively overturned between 1900 and 1926

Originally thought to be indivisible spheres unique to each element, the discovery of the electron by J.J. Thomson revealed them to be made of smaller particles. Ernest Rutherford's gold foil experiment uncovered the existence of nuclei, which Niels Bohr suggested were surrounded by electrons in fixed orbits. By applying quantum mechanics, Erwin Schrödinger replaced orbits with probability clouds.

The history of chemistry up to World War I, from alchemists seeking gold to probing atomic structure

Those involved in the predecessor of the modern scientific discipline engaged in experimentation to develop recipes that would transform ordinary matter into gold and to create medicines, cosmetics, dyes, and alloys. Over the course of centuries, scientists identified unique elements, organized them based on their properties in the periodic table, and eventually developed the technology to discover the internal structure of atoms.

The quantum model of the atom resulted from over two millennia of scientific thinking

In 440 BCE, Democritus proposed that everything was made up of tiny particles surrounded by empty space, which varied in size and shape based on the substance's properties. It was not until the 20th century that experimental evidence validated elements of Democritus' model.

The simple grandeur of atomic theory

Is the universe made up of a continuous substance, or a finite amount of tiny, indivisible atoms? The atomic hypothesis, largely vindicated in the 20th century, was forgotten for nearly 2,000 years after first being formulated by the Greek philosopher Democritus. Learn more about the theory and its implications for science and human life with this reflective essay.

Build atoms to learn about atomic number, mass number, and charge notations

In this simulation, users can add protons, neutrons, and electrons to create atoms, view their stability and atomic configurations, and identify how the amounts of these subatomic particles are detailed around the abbreviation for the resulting element using AZE notation.

The world's first artificial element, technetium, was discovered 68 years after its existence was predicted in order to fill a gap in the periodic table.

The outermost shell of electrons in an atom dictates how it bonds to other atoms, including those of the same element, and the properties of the materials composed of those atoms.

Ernest Rutherford's gold foil and nitrogen experiments revealed nuclear structure

Observing high-angle deflections when alpha particles were fired at gold foil led to an atomic model with a dense, positively charged nucleus. Firing those particles at nitrogen resulted in the emission of hydrogen nuclei—protons—leading to the discovery of the subatomic particle.

An explanation of isotopes, which can help scientists trace food, water, and farming choices

Atoms of the same element have the same number of protons, but experiments showed that atoms of the same element can move through electromagnetic fields as if they had different masses. These differences in mass come from variations in the number of neutrons, which contribute to the stability of atoms by providing a buffer to the repulsion between protons.

Unusually stable, undiscovered elements may exist near atomic number 126

While heavier elements like uranium and plutonium are unstable and decay quickly, simulations suggest a pocket of stability exists for elements with approximately 126 protons and 184 neutrons. Such elements may have practical applications, such as americium, a synthetic element used in smoke detectors.

An overview of atomic composition, scale, and structure, which is almost all 'empty' space

It takes about 500,000 carbon atoms lined up next to one another to span the thickness of human hair, and over 99.9994% of the mass of each is contained in the nucleus. About 99.999999999999% of an atom's volume lies outside this nucleus, where electrons exist in clouds of probability. Removing these clouds, the Empire State Building would be the size of a rice grain.

Build atomic nuclei to explore their instability and resulting radioactive decay

In this simulation, users can add protons and neutrons to create an atomic nucleus, view its half-life and decay options, and identify patterns in how specific combinations of particles create extremely stable nuclei, from which the nuclear shell model of stability emerged.

Elements, isotopes, and ions can be identified by the number of protons, neutrons, and electrons within the atoms that make up a substance.

The discovery of the neutron paved the way for nuclear weapons

In 1932, James Chadwick discovered the subatomic particle when trying to explain the radiation emitted by beryllium after it was bombarded with alpha particles. The radiation’s ability to eject protons from a target suggested a chargeless particle with slightly more mass than a proton.

How scientists determine elemental composition based on the light emitted by cooling atoms

When electrons within an atom drop to a lower energy level closer to the nucleus, they lose energy and produce light with energy equal to the difference between the two energy levels. Because these levels and the corresponding emitted light are unique to each element, the light serves as a unique signature that can be compared to known lab samples for identification.

Once called 'aces,' quarks are fundamental pieces of matter that combine to create over 100 known composite particles, including the proton and neutron.

The Curies developed a way to measure radioactivity in an old medical dissecting room

Despite lacking proper laboratory conditions, Marie and Pierre built an ionization chamber and a piezoelectric quartz electrometer to measure the amount of charged particles released by radiation, with a sensitivity of ten-trillionth of an ampere. Substances with different emission rates indicated different elements.

Antimatter was predicted to exist four years before it was observed, though the mathematics responsible for the prediction described it as matter with negative energy.

How chemical bonds between atoms form molecules and large geometric structures

In ionic bonding, one atom transfers at least one electron to another atom, forming two atoms of opposite charge. These atoms attract one another and can stack up in a 3D grid called a lattice. Covalent bonding, where electrons are instead shared, can produce enormous molecules, such as the two found in human chromosome 13, which each contain 37 billion atoms.

The deceptively simple proton

Take a visual deep-dive into the proton, a near-fundamental—but deceivingly simple—building block of nature. Among other beguiling characteristics, the particle can't be described by its constituent particles (quarks), but rather exists in a...

The Standard Model reveals an underlying organization to the universe

Using the framework of quantum field theory, it structures all known particles into 12 matter particles, alongside five particles that carry three of the four fundamental forces. Although remarkably precise and predictive, it cannot yet explain gravity, dark matter, or dark energy.

Distinguishing polar and nonpolar molecules and why charges get distributed unevenly in molecules

Because each element has a unique number of protons and configuration where electrons exist, they attract electrons that are shared with other elements in chemical bonds to varying degrees. When this attraction—electronegativity—varies between two bonded elements, electrons are more likely to be near the more electronegative element and away from the less electronegative element. This can create regions of opposite charge, or poles, and thus polar molecules.

Watson and Crick revealed DNA's double-helix structure using others' key findings

Their 1953 model, made from cardboard cutouts, explained how DNA stores genetic information through base pairing. Rather than experimenting and collecting their own data, they incorporated patterns and data from other scientists through trial and error.

Explore all the particles that make up the Standard Model

This interactive organizes all the particles of matter and force in the Standard Model alongside the Higgs boson. Clicking on any particle will display a brief description and several properties, such as discovery year, mass, and charge.

More than 90% of the atoms in the human body were forged by stars, with almost three-quarters originating from the explosion of massive stars.

Before discovering cells, life was believed to emerge suddenly from inorganic matter

Popularized by Aristotle in the 4th century BCE, spontaneous generation was used to explain phenomena like mice appearing in seemingly sealed grain storage. The invention of the compound microscope in the late 16th century led to the identification of cells as the basic unit of life, but it was not until 1855 that their origin from preexisting cells was established.

Smaller than atoms—what are quarks?

One of humanity’s eternal questions surrounds what we are fundamentally made of. Many ancient philosophies believed in a set of classical elements: from water, air, fire and earth of ancient Greeks; to…

The discovery of nuclear fission was facilitated by the discovery of the neutron

The discovery of the neutron provided scientists with a particle that could penetrate the nucleus and advance atomic physics. Otto Hahn was the sole Nobel recipient for the discovery of fission, despite collaborating with Lise Meitner and Fritz Strassmann.

Benjamin Franklin described a series of static electricity storage jars as 'batteries'

Discovered over 50 years before the first electrochemical cell was invented, Leyden jars stored electric charge between the metals inside and outside a liquid-filled container. Franklin was the first to use the term "battery" in an electrical sense, though his multiple-jar device—lacking chemical reactions—was actually a series of capacitors.

View 3D renderings of atomic orbitals created with quantum mechanics

Scientists use the Schrödinger equation to determine how a system governed by a wavefunction—an equation that predicts the probability of certain outcomes—evolves with time. Computers can animate atomic structure and behavior by depicting the wavefunction as a fluid that guides a particle, like water moving a speck of dust.

Why quantum mechanics causes disagreement on where the edge of an atom is located

The quantum model of the atom describes it as having a dense nucleus at its center, surrounded by electrons in probability clouds where they are most likely to be found. The fundamental uncertainty of these clouds has led to various methods and resulting measurements of the atomic radius. (Some readers may experience a paywall.)

The one-electron theory describes the universe as having only one electron

The thought experiment explains why every electron has the same charge and mass as every other electron, and describes every positron—the antimatter version of the electron—as that same electron traveling backwards in time. Among other foundational challenges, the model suggests that the universe contains equal numbers of electrons and positrons, yet normal matter is much more common than antimatter.

In 1880, Jacques and Pierre Curie discovered that electricity could be produced by striking certain materials—the piezoelectric effect—a phenomenon that is seen in barbecue lighters.

Before 1932, when particle accelerators were first used for nuclear research, scientists relied on naturally radioactive substances to advance their understanding of the atomic nucleus.

How atomic clocks have been used to measure the universe's fundamental constants

Atoms behave according to a set of parameters that scientists have determined give reality its properties. For example, the fine-structure constant, α, quantifies the strength of interactions between charged particles. Since the light emitted by atoms as they move between energy levels is affected by α, analyzing these emissions—the basis of atomic clocks—using different atoms helps calculate α.

View a ranking of the masses of fundamental particles, from the massless photon to the top quark, and a timeline of their discoveries.

An overview of helium, the nonrenewable resource that's lighter than air

The second element in the periodic table naturally forms deep underground over the course of billions of years through the decay of radioactive elements, but it is used and lost to space at rates faster than it is generated. Because of this and its extensive applications in scientific technologies, scientists continue to seek avenues for its exploration, storage, and recycling.

Similarities in reactivity complicate separating rare earths from ores

The proximity of these elements in the periodic table mean they have similar electron structure and require complex separation processes during processing. However, their uncommon magnetic, luminescent, and electrical properties make them invaluable for critical industrial applications.

Italian physicist Enrico Fermi (1901–1954) on the Standard Model

"If I could remember the name of all these particles, I'd be a botanist."

How the nuclear shell model explains the stability or radioactivity of atomic nuclei

When the number of protons and neutrons completely fills shells within the nucleus, the binding energy that prevents these particles from being pulled apart increases. These are called "magic numbers," and they produce atoms with exceptionally stable nuclear configurations.

Pierre Curie's knowledge of electromagnetism helped decipher radioactivity

Alongside his brother, he studied electric fields in crystals and the magnetic properties of substances, which required the construction of delicate electrometers. He would use this apparatus with Marie Curie to measure radioactive emissions and the presence of undiscovered radioactive elements.

View an infographic of the Standard Model

Much like this visualization, the theory serves to catalog almost all phenomena involving visible matter comprehensively, including organizing observed elementary particles by shared characteristics and explaining most fundamental forces and quantum properties.

How a quantum quirk allowed neutral atoms to form soon after the Big Bang

At the beginning of the universe, high-energy photons prevented atomic nuclei from combining with electrons to form neutral atoms. Rather than waiting for the universe to expand and cool completely, a rare quantum phenomenon—a two-photon transition—allowed neutral hydrogen atoms to form sooner, expediting the formation of stars, planets, and life.

View a timeline of particle discoveries through the Higgs boson in 2012

With few exceptions, the elementary particles that make up the Standard Model were theorized or predicted to exist before their eventual discovery in high-energy environments. These predictions were often the result of inferences drawn from already accepted mathematical models.

View a breakdown of the elemental composition of the major celestial bodies in the solar system.

An overview of radioactivity, which can spontaneously change one element into another

Unstable atomic nuclei can transmute into a new element—an atom with a different number of protons—by emitting an alpha particle (two protons and two neutrons) or a beta particle (an electron). The electron can emerge from the nucleus when a neutron, which has no charge, suddenly transforms into a proton and an electron, thereby maintaining zero charge before and after the transformation, but altering the original element.