How amendments to the Montreal Protocol have expanded global ozone protections

Why a Montreal Protocol amendment cut back on the replacements for CFCs

Hydrofluorocarbons were introduced in the 1990s as ozone-safe substitutes for chlorofluorocarbons and hydrochlorofluorocarbons. However, scientists later found that they trap thousands of times more thermal energy in the atmosphere than carbon dioxide does, prompting a 2016 amendment to the Protocol to phase them out.

The Montreal Protocol helped prevent significant quantities of greenhouse gas emissions

By phasing out ozone-depleting chemicals between 1990 and 2010, the Montreal Protocol prevented emissions equal to 135 gigatons of CO₂—avoiding an estimated 0.5 to 1 degrees Celsius of additional global warming by 2100.

The history of the Montreal Protocol, the only universally ratified treaty in UN history

Mario Molina and F. Sherwood Rowland discovered that chlorofluorocarbons released chlorine atoms that could break down molecules making up the protective ozone layer. Despite attempts to discredit scientists and economic concerns raised by politicians, the agreement to phase out ozone-depleting substances was signed in 1987.

View when each UN member signed the Montreal Protocol

Adopted in 1987 to phase out ozone-depleting substances, the agreement achieved universal ratification by all 197 UN member states, making it the first and only such international treaty in the UN's history.

How the Montreal Protocol supported developing nations in phasing out ozone-depleting substances

Established in 1991, the Multilateral Fund for the Montreal Protocol finances developing nations' transition to cleaner technologies. It has disbursed more than $4B across more than 140 countries and was the first financial mechanism created under an international treaty.

How a black market for banned refrigerants still threatens ozone recovery and climate progress

Despite the Montreal Protocol's success, illegal trade in chlorofluorocarbons, hydrochlorofluorocarbons, and hydrofluorocarbons persists. Driven by high profits and weak enforcement, smugglers supply banned refrigerants, causing significant ozone depletion and greenhouse gas emissions equivalent to billions of tons of carbon dioxide.

Learn why the Montreal Protocol may help prevent millions of cancer deaths

By restoring the ozone layer and reducing ultraviolet exposure, full implementation of the Montreal Protocol is expected to prevent about 443 million cases of skin cancer, 2.3 million skin cancer deaths, and 63 million cases of cataracts among Americans born from 1890 to 2100.

The ozone layer is on track to recover to pre-1980 levels by mid-century

Thanks to the Montreal Protocol, the ozone layer is steadily recovering and, according to a 2022 assessment, is expected to return to 1980 levels by 2040 globally, 2045 over the Arctic, and 2066 over Antarctica.

Hear firsthand how scientists and policymakers saved the ozone layer

In this episode, atmospheric chemist Susan Solomon and Protocol architect Stephen Andersen recount how scientific discovery, diplomacy, and public pressure drove the Montreal Protocol—and share lessons for tackling climate change.

Go inside the global effort that led to the Montreal Protocol in this narrative podcast

Nobel laureate Mario Molina and other key voices recount how science and diplomacy converged to develop a plan to close the ozone hole, offering insight into history's most successful environmental treaty.

How the Montreal Protocol made CFCs the most valuable Miami contraband after cocaine

Following the 1990s production ban, smugglers flooded Miami with illegal chlorofluorocarbons used in air conditioning. A 15-kilogram cylinder bought for $70 in Europe could sell for $242 in the US, fueling multimillion-dollar black-market trade. (Some users may experience a paywall.)

Fluorinated molecules are the most impactful, longest-lasting greenhouse gases

Developed as replacements for ozone-depleting substances in refrigeration and air conditioning systems, these compounds are released through leaks in and ongoing use of these appliances, as well as from various industrial processes. They can remain in the atmosphere for thousands of years and have warming potentials that are a thousand to tens of thousands of times greater than those of carbon dioxide.

How a skin cancerous growth shifted an initially skeptical President Reagan on the ozone crisis

While a 1985 Nature study revealing the Antarctic ozone hole jolted public concern, Reagan's administration was more focused on the Cold War than on environmental policy. His health scare and the market potential for developing alternatives to chlorofluorocarbons helped turn the tide, leading to the Montreal Protocol's unanimous ratification by a bipartisan Senate in 1988.

How sunlight helps chlorofluorocarbons destroy the ozone molecules that block solar radiation

CFCs, which are used in old refrigerants, air conditioners, and aerosol sprays, do not react with atmospheric molecules. Once they reach the stratosphere, ultraviolet radiation breaks chlorine atoms off of them, which can each break apart more than 100,000 ozone molecules, thinning Earth's protective layer against ultraviolet radiation.

The Clean Air Act became the cornerstone of modern air pollution control

Passed in 1970 and strengthened through multiple amendments, the Clean Air Act authorizes the EPA to set national air quality standards, regulate industrial and vehicle emissions, and reduce pollutants such as ozone, sulfur dioxide, and lead.

Why the ozone hole altered Southern Hemisphere jet streams and rainfall patterns

Ozone depletion over Antarctica shifted jet streams southward, drying Australia while increasing rainfall in Uruguay, Brazil, Paraguay, and Argentina. Around the turn of the millennium, these trends began to slow as the Montreal Protocol phased out ozone-depleting substances.

Watch a 1986 television special about the discovery of the ozone hole

The groundbreaking discovery of the Antarctic ozone hole in the mid-1980s marked a critical turning point, galvanizing international action to address the ozone-depleting properties of chlorofluorocarbons, which had been identified about a decade earlier. This environmental crisis was brought vividly to public attention through media pieces like this one.

How scientists earned themselves a Nobel Prize by discovering what destroyed ozone

In 1974, chemists Mario Molina and F. Sherwood Rowland showed that chlorofluorocarbons—then used as aerosol propellants, refrigerants, and industrial solvents—rise into the stratosphere and, upon being struck by ultraviolet radiation, release chlorine atoms, which break apart ozone molecules. Their work earned them the Nobel Prize in chemistry in 1995.

A UN-led treaty may establish rules to phase out plastic globally

With support from more than 175 nations, a treaty led by the United Nations is being negotiated to establish enforceable global rules for plastic production and pollution by 2025. Negotiations come as the total amount of plastic in the ocean has increased by 50% from 2017 to 2022.

Ozone protects against the sun's UV radiation and enhances the greenhouse effect

In the stratosphere, trioxygen molecules can absorb harmful ultraviolet radiation from the sun, preventing it from reaching Earth's surface, where it can harm organisms and raise surface temperatures. In the lower atmosphere, ozone acts as a greenhouse gas, trapping thermal radiation.

The EPA partners with other countries to strengthen environmental protection

Through bilateral programs on every continent, the EPA shares American environmental expertise with developing nations and economies in transition. These partnerships support air and water protection, chemical safety, and pollution control, while advancing US environmental priorities abroad.

Why the Antarctic climate enabled British scientists to discover the ozone hole

In the Antarctic stratosphere, polar conditions facilitate the formation of polar stratospheric clouds, which allow chlorine compounds from chlorofluorocarbons to accumulate. In 1985, British Antarctic Survey scientists detected massive springtime losses over Antarctica, as accumulated compounds destroyed significant amounts of ozone once sunlight returned.

Nitrous oxide is the third most significant greenhouse gas made by human activities

Emissions of this molecule increased 40% from 1980 to 2020, with atmospheric concentrations reaching levels higher than at any other time in the last 800,000 years, based on ice core records. Its warming potential is 273 times that of carbon dioxide over 100 years and remains in the atmosphere for more than a century, on average.

When signing the Paris Agreement, almost 200 nations committed to pursuing efforts to limit global warming to 1.5 degrees Celsius above preindustrial levels, based on guidance from the Intergovernmental Panel on Climate Change.

As of 2023, more than 130 nations have enacted bans or restrictions on plastic items, starting with Bangladesh's ban on plastic bags in 2002.

Yearly greenhouse gas emissions have been steadily increasing since 1850

Although greenhouse gases include methane, nitrous oxide, and most fluorinated compounds, their warming potential is often measured relative to carbon dioxide. In these units, greenhouse gas emissions have gone from 4.29 billion metric tons of carbon dioxide equivalent in 1850 to 54.43 billion metric tons in 2024.

Excluding water vapor, greenhouse gases make up less than 1% of Earth's atmosphere

Although carbon dioxide, methane, nitrous oxide, ozone, and most fluorinated gases account for only a minority of the planet's greenhouse effect due to their lower concentrations, they are more effective at trapping thermal radiation. While water vapor condenses within two weeks, other greenhouse gases linger in the atmosphere for years on average.

Oxygen and ozone molecules absorb up to 99.9% of UV radiation reaching Earth

Although they make up no more than 10 out of every million molecules in the ozone layer, ozone provides outsized protection by absorbing the most energetic wavelengths of ultraviolet radiation. This absorption increases thermal energy in the stratosphere, causing temperatures there to rise with altitude.

Methane: the other greenhouse gas

While most of the focus with respect to greenhouse gases lands on carbon dioxide, methane is the second most potent contributor. The gas, a carbon atom with four hydrogen atoms, is 25 times more potent than CO2 in terms of trapping heat over a 100...

Most of the 86,000 consumer chemicals registered with the US EPA have never received rigorous toxicity testing, though not all those are still in current use.

Why bacterial bioremediation may help counter the negative effects of past chemical solutions

Molecules such as DDT, a synthetic insecticide, and PFAS—"forever" chemicals used to make products resistant to heat, water, and grease—have historically been used across various industries but are now known to be harmful. Microbes that can convert some of these substances into nontoxic products, such as water and carbon dioxide, have already been identified, with ongoing research to find others.

The Office of Air and Radiation oversees America's clean air and climate programs

The office develops and enforces national standards for air quality, vehicle emissions, and radiation protection. In 2025, the EPA announced the closure of two key divisions under the office responsible for regulating climate and air pollution: the Office of Atmospheric Protection and the Office of Air Quality Planning and Standards.

Why Earth would become a more deadly environment without the ozone layer

The ozone layer blocks almost all of the sun's harmful, including dangerous UVC rays that can damage cells by breaking chemical bonds. Without it, rates of skin cancer, crop failures, oceanic die-offs, and widespread ecosystem collapse would increase significantly, making Earth largely uninhabitable.

Environmental regulation had bipartisan support in the 1970s

During the 1970s, Democrats and Republicans alike backed landmark environmental laws. Congress passed the Clean Air, Clean Water, and Endangered Species Acts with overwhelming bipartisan majorities—reflecting broad public agreement on protecting the environment.

Forever chemicals accumulate up the food web, with recent research indicating that apex predators have higher concentrations because they're eating prey that also have accumulated the substances.

Forever chemicals are so common that experts concluded in 2022 that it's uncertain whether limiting consumer exposure would truly reduce one's exposure to these substances, and noted it would still take years for the body to clear them.

Greenhouse gas emissions from human activity accelerate recent global warming

These gases exacerbate the greenhouse effect—warming that results when the atmosphere traps heat radiating from Earth toward space. The most abundant atmospheric greenhouse gas is carbon dioxide, which is released from the burning of fossil fuels.

The Office of Chemical Safety and Pollution Prevention regulates toxic substances

This office evaluates and manages risks from industrial chemicals and pesticides. It reviews new chemicals before they enter the market, restricts hazardous substances, and promotes safer alternatives to protect human health and the environment.

As of 2024, 13 states have plans to phase out gas-powered cars

In 2022, California adopted the Advanced Clean Cars II Act, which requires all new passenger cars, trucks, and SUVs sold to produce zero emissions by 2035. Other states adopted similar laws, joining more than 50 countries with phaseout plans.

Carbon dioxide is the most produced greenhouse gas from human activities

In 2022, about 79.7% of US greenhouse gas emissions were carbon dioxide, produced through chemical reactions in processes such as cement production and the burning of fossil fuels, solid waste, trees, and other biological materials. Methane (11.1%), nitrous oxide (6.1%), fluorinated gases (3.1%), and trace amounts of solid and liquid aerosol were also created.

The impact of greenhouse gases is assessed as a measure of Global Warming Potential

Since 1990, the Intergovernmental Panel on Climate Change has used GWP to measure how much energy 1 metric ton of a gas emits over a given period—usually 100 years—relative to 1 metric ton of carbon dioxide. By definition, carbon dioxide has a GWP of 1.

As of 2024, China is the largest overall contributor to global greenhouse gas emissions

Due to its large population, the nation's per capita emissions continue to lag behind those of the US, Canada, Russia, Australia, and Saudi Arabia. The Arab country has experienced the most significant increase in per capita greenhouse gas emissions since 1990, now leading the world at 22.8 metric tons of carbon dioxide equivalent per capita.

Greenhouse gas removal consists of a series of techniques to capture and store GHGs

These include turning biomass into charcoal for storage in soil before it decays and releases carbon dioxide, crushing CO₂-absorbing rocks—increasing exposed surface area—and spreading them across land to accelerate GHG uptake, and restoring degraded peatlands, which can store twice the amount of carbon as the average forest.

The Clean Water Act became the national standard for protecting American waters

Enacted in 1972, the Clean Water Act grants the Environmental Protection Agency the authority to regulate pollutant discharges, establish water quality standards, and oversee water pollution controls. Its scope has narrowed due to recent Supreme Court rulings.

The international trademark framework is called the Madrid Protocol

Trademarks vary from country to country, but an agreement called the Madrid Protocol allows trademark protections across more than 100 participating countries. While the Madrid Protocol expands trademark access, it doesn't necessarily grant blanket protections across the participating countries, meaning each country is still in charge of its own trademark enforcement.

Understanding the 1.5 degree Celsius climate benchmark

As more parts of the world are facing extreme weather, from high temperatures to increased natural disasters, there is much debate about what can be done. MIT News explores and explains the 1.5-degree benchmark for limiting the effects of climate change. Read to understand where the planet stands in relation to this threshold and what can be done at the global, regional, and personal levels to “keep 1.5 alive.”

The international agreement to address antimicrobial resistance

Antimicrobial resistance has become an increasingly glaring problem for both health and agriculture. In 2024, the United Nations announced a new suite of clear actions and targets that—taken together with existing efforts—can help address superbugs in a meaningful way and on a global scale. This page from the UN lays out these efforts, with links to additional information on the many aspects of the initiative.

Climate change skepticism and business interests politicized environmental protection

The EPA was created under a Republican administration with bipartisan support in response to overwhelming public demand during a time of visible pollution and environmental crises. Beginning with President Reagan, the agency was recast as burdensome, and environmental regulations have been gradually rolled back.

Los Angeles once suffered some of the worst smog on Earth

From the 1940s through the 1960s, Los Angeles was blanketed by dense, eye-burning smog so severe that drivers sometimes couldn't see traffic lights. The issue led to the nation's first local air pollution controls and inspired the passage of the 1970 Clean Air Act.

Track the current size of the Antarctic ozone hole with NASA's real-time data

NASA's Ozone Watch provides daily satellite images and time-lapse videos showing the extent of the Antarctic ozone hole. Each spring, scientists monitor its size and depth to measure recovery progress and detect any new chemical or climatic disruptions.