Why a Montreal Protocol amendment cut back on the replacements for CFCs

How amendments to the Montreal Protocol have expanded global ozone protections

Since 1990, five major amendments—London, Copenhagen, Montreal, Beijing, and Kigali—have accelerated chemical phase-outs, added new substances, such as hydrochlorofluorocarbons, and tightened enforcement.

The Montreal Protocol helped prevent significant quantities of greenhouse gas emissions

By phasing out ozone-depleting chemicals between 1990 and 2010, the Montreal Protocol prevented emissions equal to 135 gigatons of CO₂—avoiding an estimated 0.5 to 1 degrees Celsius of additional global warming by 2100.

The history of the Montreal Protocol, the only universally ratified treaty in UN history

Mario Molina and F. Sherwood Rowland discovered that chlorofluorocarbons released chlorine atoms that could break down molecules making up the protective ozone layer. Despite attempts to discredit scientists and economic concerns raised by politicians, the agreement to phase out ozone-depleting substances was signed in 1987.

How a black market for banned refrigerants still threatens ozone recovery and climate progress

Despite the Montreal Protocol's success, illegal trade in chlorofluorocarbons, hydrochlorofluorocarbons, and hydrofluorocarbons persists. Driven by high profits and weak enforcement, smugglers supply banned refrigerants, causing significant ozone depletion and greenhouse gas emissions equivalent to billions of tons of carbon dioxide.

How sunlight helps chlorofluorocarbons destroy the ozone molecules that block solar radiation

CFCs, which are used in old refrigerants, air conditioners, and aerosol sprays, do not react with atmospheric molecules. Once they reach the stratosphere, ultraviolet radiation breaks chlorine atoms off of them, which can each break apart more than 100,000 ozone molecules, thinning Earth's protective layer against ultraviolet radiation.

How the Montreal Protocol supported developing nations in phasing out ozone-depleting substances

Established in 1991, the Multilateral Fund for the Montreal Protocol finances developing nations' transition to cleaner technologies. It has disbursed more than $4B across more than 140 countries and was the first financial mechanism created under an international treaty.

Fluorinated molecules are the most impactful, longest-lasting greenhouse gases

Developed as replacements for ozone-depleting substances in refrigeration and air conditioning systems, these compounds are released through leaks in and ongoing use of these appliances, as well as from various industrial processes. They can remain in the atmosphere for thousands of years and have warming potentials that are a thousand to tens of thousands of times greater than those of carbon dioxide.

How the Montreal Protocol made CFCs the most valuable Miami contraband after cocaine

Following the 1990s production ban, smugglers flooded Miami with illegal chlorofluorocarbons used in air conditioning. A 15-kilogram cylinder bought for $70 in Europe could sell for $242 in the US, fueling multimillion-dollar black-market trade. (Some users may experience a paywall.)

View when each UN member signed the Montreal Protocol

Adopted in 1987 to phase out ozone-depleting substances, the agreement achieved universal ratification by all 197 UN member states, making it the first and only such international treaty in the UN's history.

Learn why the Montreal Protocol may help prevent millions of cancer deaths

By restoring the ozone layer and reducing ultraviolet exposure, full implementation of the Montreal Protocol is expected to prevent about 443 million cases of skin cancer, 2.3 million skin cancer deaths, and 63 million cases of cataracts among Americans born from 1890 to 2100.

The ozone layer is on track to recover to pre-1980 levels by mid-century

Thanks to the Montreal Protocol, the ozone layer is steadily recovering and, according to a 2022 assessment, is expected to return to 1980 levels by 2040 globally, 2045 over the Arctic, and 2066 over Antarctica.

How scientists earned themselves a Nobel Prize by discovering what destroyed ozone

In 1974, chemists Mario Molina and F. Sherwood Rowland showed that chlorofluorocarbons—then used as aerosol propellants, refrigerants, and industrial solvents—rise into the stratosphere and, upon being struck by ultraviolet radiation, release chlorine atoms, which break apart ozone molecules. Their work earned them the Nobel Prize in chemistry in 1995.

Hear firsthand how scientists and policymakers saved the ozone layer

In this episode, atmospheric chemist Susan Solomon and Protocol architect Stephen Andersen recount how scientific discovery, diplomacy, and public pressure drove the Montreal Protocol—and share lessons for tackling climate change.

How a skin cancerous growth shifted an initially skeptical President Reagan on the ozone crisis

While a 1985 Nature study revealing the Antarctic ozone hole jolted public concern, Reagan's administration was more focused on the Cold War than on environmental policy. His health scare and the market potential for developing alternatives to chlorofluorocarbons helped turn the tide, leading to the Montreal Protocol's unanimous ratification by a bipartisan Senate in 1988.

Why the Antarctic climate enabled British scientists to discover the ozone hole

In the Antarctic stratosphere, polar conditions facilitate the formation of polar stratospheric clouds, which allow chlorine compounds from chlorofluorocarbons to accumulate. In 1985, British Antarctic Survey scientists detected massive springtime losses over Antarctica, as accumulated compounds destroyed significant amounts of ozone once sunlight returned.

Watch a 1986 television special about the discovery of the ozone hole

The groundbreaking discovery of the Antarctic ozone hole in the mid-1980s marked a critical turning point, galvanizing international action to address the ozone-depleting properties of chlorofluorocarbons, which had been identified about a decade earlier. This environmental crisis was brought vividly to public attention through media pieces like this one.

Go inside the global effort that led to the Montreal Protocol in this narrative podcast

Nobel laureate Mario Molina and other key voices recount how science and diplomacy converged to develop a plan to close the ozone hole, offering insight into history's most successful environmental treaty.

Why the ozone hole altered Southern Hemisphere jet streams and rainfall patterns

Ozone depletion over Antarctica shifted jet streams southward, drying Australia while increasing rainfall in Uruguay, Brazil, Paraguay, and Argentina. Around the turn of the millennium, these trends began to slow as the Montreal Protocol phased out ozone-depleting substances.

Excluding water vapor, greenhouse gases make up less than 1% of Earth's atmosphere

Although carbon dioxide, methane, nitrous oxide, ozone, and most fluorinated gases account for only a minority of the planet's greenhouse effect due to their lower concentrations, they are more effective at trapping thermal radiation. While water vapor condenses within two weeks, other greenhouse gases linger in the atmosphere for years on average.

Forever chemicals are so common that experts concluded in 2022 that it's uncertain whether limiting consumer exposure would truly reduce one's exposure to these substances, and noted it would still take years for the body to clear them.

Methane: the other greenhouse gas

While most of the focus with respect to greenhouse gases lands on carbon dioxide, methane is the second most potent contributor. The gas, a carbon atom with four hydrogen atoms, is 25 times more potent than CO2 in terms of trapping heat over a 100...

Ozone protects against the sun's UV radiation and enhances the greenhouse effect

In the stratosphere, trioxygen molecules can absorb harmful ultraviolet radiation from the sun, preventing it from reaching Earth's surface, where it can harm organisms and raise surface temperatures. In the lower atmosphere, ozone acts as a greenhouse gas, trapping thermal radiation.

Most of the 86,000 consumer chemicals registered with the US EPA have never received rigorous toxicity testing, though not all those are still in current use.

Why bacterial bioremediation may help counter the negative effects of past chemical solutions

Molecules such as DDT, a synthetic insecticide, and PFAS—"forever" chemicals used to make products resistant to heat, water, and grease—have historically been used across various industries but are now known to be harmful. Microbes that can convert some of these substances into nontoxic products, such as water and carbon dioxide, have already been identified, with ongoing research to find others.

Carbon markets incentivize companies to cut emissions but require high carbon prices

To reduce greenhouse gas emissions, a cap-and-trade system issues a limited number of emissions permits—carbon credits—that decrease each year, cutting into a company's profits if it does not reduce emissions and must buy permits from others. However, cheap permits and minimal fines for lacking permits have reduced the system's effectiveness.

Yearly greenhouse gas emissions have been steadily increasing since 1850

Although greenhouse gases include methane, nitrous oxide, and most fluorinated compounds, their warming potential is often measured relative to carbon dioxide. In these units, greenhouse gas emissions have gone from 4.29 billion metric tons of carbon dioxide equivalent in 1850 to 54.43 billion metric tons in 2024.

Teflon was an accidental discovery by a DuPont scientist in the 1930s resulting from efforts to create a safe refrigerant.

Oxygen and ozone molecules absorb up to 99.9% of UV radiation reaching Earth

Although they make up no more than 10 out of every million molecules in the ozone layer, ozone provides outsized protection by absorbing the most energetic wavelengths of ultraviolet radiation. This absorption increases thermal energy in the stratosphere, causing temperatures there to rise with altitude.

Forever chemicals accumulate up the food web, with recent research indicating that apex predators have higher concentrations because they're eating prey that also have accumulated the substances.

Why Earth would become a more deadly environment without the ozone layer

The ozone layer blocks almost all of the sun's harmful, including dangerous UVC rays that can damage cells by breaking chemical bonds. Without it, rates of skin cancer, crop failures, oceanic die-offs, and widespread ecosystem collapse would increase significantly, making Earth largely uninhabitable.

When signing the Paris Agreement, almost 200 nations committed to pursuing efforts to limit global warming to 1.5 degrees Celsius above preindustrial levels, based on guidance from the Intergovernmental Panel on Climate Change.

Nitrous oxide is the third most significant greenhouse gas made by human activities

Emissions of this molecule increased 40% from 1980 to 2020, with atmospheric concentrations reaching levels higher than at any other time in the last 800,000 years, based on ice core records. Its warming potential is 273 times that of carbon dioxide over 100 years and remains in the atmosphere for more than a century, on average.

Carbon dioxide is the most produced greenhouse gas from human activities

In 2022, about 79.7% of US greenhouse gas emissions were carbon dioxide, produced through chemical reactions in processes such as cement production and the burning of fossil fuels, solid waste, trees, and other biological materials. Methane (11.1%), nitrous oxide (6.1%), fluorinated gases (3.1%), and trace amounts of solid and liquid aerosol were also created.

The Clean Air Act became the cornerstone of modern air pollution control

Passed in 1970 and strengthened through multiple amendments, the Clean Air Act authorizes the EPA to set national air quality standards, regulate industrial and vehicle emissions, and reduce pollutants such as ozone, sulfur dioxide, and lead.

Greenhouse gas removal consists of a series of techniques to capture and store GHGs

These include turning biomass into charcoal for storage in soil before it decays and releases carbon dioxide, crushing CO₂-absorbing rocks—increasing exposed surface area—and spreading them across land to accelerate GHG uptake, and restoring degraded peatlands, which can store twice the amount of carbon as the average forest.

Why helium helped preserve the US' founding documents, but was later replaced

In 1951, the Charters of Freedom were stored in glass and metal cases filled with helium, which would not chemically react with the documents. After microscopic cracks were identified in the glass through which helium could leak out of and—experts feared—pollutants could infiltrate, new encasements made of aluminum, titanium, and argon replaced the old system in 2003.

Used since the 1940s, 'forever chemicals' include thousands of different types of substances routinely integrated into industry and consumer products, yet research suggests they can accumulate in the body over time.

Since 2026, the Large Hadron Collider has provided heat to thousands of French homes and businesses through a system that harnesses hot water from the accelerator's cooling circuits.

Although PFAS, or forever chemicals, are intentionally designed to be extremely stable and long-lasting because of their strong carbon-fluorine bonds, these bonds can be broken by heat, plasma, and supercritical water.

The impact of greenhouse gases is assessed as a measure of Global Warming Potential

Since 1990, the Intergovernmental Panel on Climate Change has used GWP to measure how much energy 1 metric ton of a gas emits over a given period—usually 100 years—relative to 1 metric ton of carbon dioxide. By definition, carbon dioxide has a GWP of 1.

Greenhouse gas emissions from human activity accelerate recent global warming

These gases exacerbate the greenhouse effect—warming that results when the atmosphere traps heat radiating from Earth toward space. The most abundant atmospheric greenhouse gas is carbon dioxide, which is released from the burning of fossil fuels.

A UN-led treaty may establish rules to phase out plastic globally

With support from more than 175 nations, a treaty led by the United Nations is being negotiated to establish enforceable global rules for plastic production and pollution by 2025. Negotiations come as the total amount of plastic in the ocean has increased by 50% from 2017 to 2022.

As of 2024, 13 states have plans to phase out gas-powered cars

In 2022, California adopted the Advanced Clean Cars II Act, which requires all new passenger cars, trucks, and SUVs sold to produce zero emissions by 2035. Other states adopted similar laws, joining more than 50 countries with phaseout plans.

Project STORMFURY explored modifying hurricanes with silver iodide

Between 1962 and 1983, researchers at the National Oceanic and Atmospheric Administration investigated whether weakening and controlling hurricanes was possible. The investigation showed very few hurricanes met the criteria for modification, despite successfully weakening two storms.

Carbon dioxide acts as a 'control knob' for Earth's climate

Although Earth's ice ages were primarily triggered by slow changes in the planet's orbit—known as Milankovitch cycles—these changes do not explain the extreme temperature swings during glacial periods. Carbon dioxide acts as a feedback mechanism, intensifying both cooling during ice ages and warming during their ends by reinforcing the initial changes sparked by orbital shifts.

Watch 'Last Week Tonight' explore the risks of 'forever chemicals,' a group of human-made chemicals used in everyday products to make them resistant to water, stains, grease, and heat. (Warning: language.)

By absorbing 90% of the thermal energy trapped by greenhouse gases, oceans are providing increasingly more energy to power the rapid strengthening of hurricanes.

Carbon sinks absorb more greenhouse gases than they produce

The largest on Earth are oceans, which capture 25% of all carbon emissions and 90% of excess atmospheric thermal radiation while generating half of the world's oxygen. Wildfires and deforestation have reduced forests' net sink capacity, though fungi are believed to capture and store over a third of global carbon emissions.

Revelations that apples were sprayed with the chemical Alar led to its ban in the 1980s

Almost three decades after Rachel Carson’s “Silent Spring,” a “60 Minutes” segment on the use of Alar, a chemical sprayed on apples, drew national attention and inspired supermarkets and schools to remove apples from their shelves and cafeterias. That same year, the Environmental Protection Agency took action against the use of the chemical in food.

As of 2023, more than 130 nations have enacted bans or restrictions on plastic items, starting with Bangladesh's ban on plastic bags in 2002.