The Montreal Protocol helped prevent significant quantities of greenhouse gas emissions

How amendments to the Montreal Protocol have expanded global ozone protections

Since 1990, five major amendments—London, Copenhagen, Montreal, Beijing, and Kigali—have accelerated chemical phase-outs, added new substances, such as hydrochlorofluorocarbons, and tightened enforcement.

The history of the Montreal Protocol, the only universally ratified treaty in UN history

Mario Molina and F. Sherwood Rowland discovered that chlorofluorocarbons released chlorine atoms that could break down molecules making up the protective ozone layer. Despite attempts to discredit scientists and economic concerns raised by politicians, the agreement to phase out ozone-depleting substances was signed in 1987.

How the Montreal Protocol supported developing nations in phasing out ozone-depleting substances

Established in 1991, the Multilateral Fund for the Montreal Protocol finances developing nations' transition to cleaner technologies. It has disbursed more than $4B across more than 140 countries and was the first financial mechanism created under an international treaty.

Why a Montreal Protocol amendment cut back on the replacements for CFCs

Hydrofluorocarbons were introduced in the 1990s as ozone-safe substitutes for chlorofluorocarbons and hydrochlorofluorocarbons. However, scientists later found that they trap thousands of times more thermal energy in the atmosphere than carbon dioxide does, prompting a 2016 amendment to the Protocol to phase them out.

Learn why the Montreal Protocol may help prevent millions of cancer deaths

By restoring the ozone layer and reducing ultraviolet exposure, full implementation of the Montreal Protocol is expected to prevent about 443 million cases of skin cancer, 2.3 million skin cancer deaths, and 63 million cases of cataracts among Americans born from 1890 to 2100.

View when each UN member signed the Montreal Protocol

Adopted in 1987 to phase out ozone-depleting substances, the agreement achieved universal ratification by all 197 UN member states, making it the first and only such international treaty in the UN's history.

The ozone layer is on track to recover to pre-1980 levels by mid-century

Thanks to the Montreal Protocol, the ozone layer is steadily recovering and, according to a 2022 assessment, is expected to return to 1980 levels by 2040 globally, 2045 over the Arctic, and 2066 over Antarctica.

How a black market for banned refrigerants still threatens ozone recovery and climate progress

Despite the Montreal Protocol's success, illegal trade in chlorofluorocarbons, hydrochlorofluorocarbons, and hydrofluorocarbons persists. Driven by high profits and weak enforcement, smugglers supply banned refrigerants, causing significant ozone depletion and greenhouse gas emissions equivalent to billions of tons of carbon dioxide.

Go inside the global effort that led to the Montreal Protocol in this narrative podcast

Nobel laureate Mario Molina and other key voices recount how science and diplomacy converged to develop a plan to close the ozone hole, offering insight into history's most successful environmental treaty.

Fluorinated molecules are the most impactful, longest-lasting greenhouse gases

Developed as replacements for ozone-depleting substances in refrigeration and air conditioning systems, these compounds are released through leaks in and ongoing use of these appliances, as well as from various industrial processes. They can remain in the atmosphere for thousands of years and have warming potentials that are a thousand to tens of thousands of times greater than those of carbon dioxide.

Hear firsthand how scientists and policymakers saved the ozone layer

In this episode, atmospheric chemist Susan Solomon and Protocol architect Stephen Andersen recount how scientific discovery, diplomacy, and public pressure drove the Montreal Protocol—and share lessons for tackling climate change.

How the Montreal Protocol made CFCs the most valuable Miami contraband after cocaine

Following the 1990s production ban, smugglers flooded Miami with illegal chlorofluorocarbons used in air conditioning. A 15-kilogram cylinder bought for $70 in Europe could sell for $242 in the US, fueling multimillion-dollar black-market trade. (Some users may experience a paywall.)

Yearly greenhouse gas emissions have been steadily increasing since 1850

Although greenhouse gases include methane, nitrous oxide, and most fluorinated compounds, their warming potential is often measured relative to carbon dioxide. In these units, greenhouse gas emissions have gone from 4.29 billion metric tons of carbon dioxide equivalent in 1850 to 54.43 billion metric tons in 2024.

The impact of greenhouse gases is assessed as a measure of Global Warming Potential

Since 1990, the Intergovernmental Panel on Climate Change has used GWP to measure how much energy 1 metric ton of a gas emits over a given period—usually 100 years—relative to 1 metric ton of carbon dioxide. By definition, carbon dioxide has a GWP of 1.

When signing the Paris Agreement, almost 200 nations committed to pursuing efforts to limit global warming to 1.5 degrees Celsius above preindustrial levels, based on guidance from the Intergovernmental Panel on Climate Change.

Ozone protects against the sun's UV radiation and enhances the greenhouse effect

In the stratosphere, trioxygen molecules can absorb harmful ultraviolet radiation from the sun, preventing it from reaching Earth's surface, where it can harm organisms and raise surface temperatures. In the lower atmosphere, ozone acts as a greenhouse gas, trapping thermal radiation.

How a skin cancerous growth shifted an initially skeptical President Reagan on the ozone crisis

While a 1985 Nature study revealing the Antarctic ozone hole jolted public concern, Reagan's administration was more focused on the Cold War than on environmental policy. His health scare and the market potential for developing alternatives to chlorofluorocarbons helped turn the tide, leading to the Montreal Protocol's unanimous ratification by a bipartisan Senate in 1988.

How sunlight helps chlorofluorocarbons destroy the ozone molecules that block solar radiation

CFCs, which are used in old refrigerants, air conditioners, and aerosol sprays, do not react with atmospheric molecules. Once they reach the stratosphere, ultraviolet radiation breaks chlorine atoms off of them, which can each break apart more than 100,000 ozone molecules, thinning Earth's protective layer against ultraviolet radiation.

Nitrous oxide is the third most significant greenhouse gas made by human activities

Emissions of this molecule increased 40% from 1980 to 2020, with atmospheric concentrations reaching levels higher than at any other time in the last 800,000 years, based on ice core records. Its warming potential is 273 times that of carbon dioxide over 100 years and remains in the atmosphere for more than a century, on average.

Excluding water vapor, greenhouse gases make up less than 1% of Earth's atmosphere

Although carbon dioxide, methane, nitrous oxide, ozone, and most fluorinated gases account for only a minority of the planet's greenhouse effect due to their lower concentrations, they are more effective at trapping thermal radiation. While water vapor condenses within two weeks, other greenhouse gases linger in the atmosphere for years on average.

Greenhouse gas emissions from human activities have contributed to global warming

A 2021 report from the Intergovernmental Panel on Climate Change found that such emissions were responsible for approximately 1.1 degrees Celsius (2.0 degrees Fahrenheit) of warming since 1850-1900. Without rapid, large-scale reductions in emissions, temperatures are expected to continue to rise, leading to more extreme weather events.

How scientists earned themselves a Nobel Prize by discovering what destroyed ozone

In 1974, chemists Mario Molina and F. Sherwood Rowland showed that chlorofluorocarbons—then used as aerosol propellants, refrigerants, and industrial solvents—rise into the stratosphere and, upon being struck by ultraviolet radiation, release chlorine atoms, which break apart ozone molecules. Their work earned them the Nobel Prize in chemistry in 1995.

Methane: the other greenhouse gas

While most of the focus with respect to greenhouse gases lands on carbon dioxide, methane is the second most potent contributor. The gas, a carbon atom with four hydrogen atoms, is 25 times more potent than CO2 in terms of trapping heat over a 100...

Watch a 1986 television special about the discovery of the ozone hole

The groundbreaking discovery of the Antarctic ozone hole in the mid-1980s marked a critical turning point, galvanizing international action to address the ozone-depleting properties of chlorofluorocarbons, which had been identified about a decade earlier. This environmental crisis was brought vividly to public attention through media pieces like this one.

Why the ozone hole altered Southern Hemisphere jet streams and rainfall patterns

Ozone depletion over Antarctica shifted jet streams southward, drying Australia while increasing rainfall in Uruguay, Brazil, Paraguay, and Argentina. Around the turn of the millennium, these trends began to slow as the Montreal Protocol phased out ozone-depleting substances.

Carbon dioxide is the most produced greenhouse gas from human activities

In 2022, about 79.7% of US greenhouse gas emissions were carbon dioxide, produced through chemical reactions in processes such as cement production and the burning of fossil fuels, solid waste, trees, and other biological materials. Methane (11.1%), nitrous oxide (6.1%), fluorinated gases (3.1%), and trace amounts of solid and liquid aerosol were also created.

Greenhouse gas removal consists of a series of techniques to capture and store GHGs

These include turning biomass into charcoal for storage in soil before it decays and releases carbon dioxide, crushing CO₂-absorbing rocks—increasing exposed surface area—and spreading them across land to accelerate GHG uptake, and restoring degraded peatlands, which can store twice the amount of carbon as the average forest.

Oxygen and ozone molecules absorb up to 99.9% of UV radiation reaching Earth

Although they make up no more than 10 out of every million molecules in the ozone layer, ozone provides outsized protection by absorbing the most energetic wavelengths of ultraviolet radiation. This absorption increases thermal energy in the stratosphere, causing temperatures there to rise with altitude.

Across a 20-year period, methane has more than 80 times the warming potential of CO₂

However, this greenhouse gas lasts only about 12 years in the atmosphere, much less than the centuries or more that carbon dioxide can persist. Methane is produced primarily during the production, storage, and transmission of coal, natural gas, and oil, as well as from the digestive processes of domestic livestock.

A UN-led treaty may establish rules to phase out plastic globally

With support from more than 175 nations, a treaty led by the United Nations is being negotiated to establish enforceable global rules for plastic production and pollution by 2025. Negotiations come as the total amount of plastic in the ocean has increased by 50% from 2017 to 2022.

Greenhouse gas emissions from human activity accelerate recent global warming

These gases exacerbate the greenhouse effect—warming that results when the atmosphere traps heat radiating from Earth toward space. The most abundant atmospheric greenhouse gas is carbon dioxide, which is released from the burning of fossil fuels.

What should you eat to help the climate?

Climate change is impacted by what we eat and what we don't eat. Did you know, for instance, that livestock accounts for 14.5 percent of the world’s greenhouse gases each year? Eating less meat and dairy and more protein-rich plants like beans,...

Carbon dioxide acts as a 'control knob' for Earth's climate

Although Earth's ice ages were primarily triggered by slow changes in the planet's orbit—known as Milankovitch cycles—these changes do not explain the extreme temperature swings during glacial periods. Carbon dioxide acts as a feedback mechanism, intensifying both cooling during ice ages and warming during their ends by reinforcing the initial changes sparked by orbital shifts.

Carbon sinks absorb more greenhouse gases than they produce

The largest on Earth are oceans, which capture 25% of all carbon emissions and 90% of excess atmospheric thermal radiation while generating half of the world's oxygen. Wildfires and deforestation have reduced forests' net sink capacity, though fungi are believed to capture and store over a third of global carbon emissions.

Carbon markets incentivize companies to cut emissions but require high carbon prices

To reduce greenhouse gas emissions, a cap-and-trade system issues a limited number of emissions permits—carbon credits—that decrease each year, cutting into a company's profits if it does not reduce emissions and must buy permits from others. However, cheap permits and minimal fines for lacking permits have reduced the system's effectiveness.

Watch a visualization of New York City's greenhouse gas emissions

About 1.72 tons of carbon dioxide-equivalent gases are released into the atmosphere every second in the Big Apple, enough to fill a balloon 33 feet across at standard pressure and 59 degrees Fahrenheit. After a day, the spheres would pile up into a pyramid whose base spans from the bottom of Manhattan to the south of Central Park.

Arctic permafrost may store twice as much carbon as the entire atmosphere

Rising greenhouse gas concentrations are expected to continue to increase average global temperatures and threaten to thaw ground that has been frozen for thousands of years. The release of greenhouse gases from remnant organic matter would exacerbate the greenhouse effect, creating a positive feedback loop.

Why the Antarctic climate enabled British scientists to discover the ozone hole

In the Antarctic stratosphere, polar conditions facilitate the formation of polar stratospheric clouds, which allow chlorine compounds from chlorofluorocarbons to accumulate. In 1985, British Antarctic Survey scientists detected massive springtime losses over Antarctica, as accumulated compounds destroyed significant amounts of ozone once sunlight returned.

Understanding the 1.5 degree Celsius climate benchmark

As more parts of the world are facing extreme weather, from high temperatures to increased natural disasters, there is much debate about what can be done. MIT News explores and explains the 1.5-degree benchmark for limiting the effects of climate change. Read to understand where the planet stands in relation to this threshold and what can be done at the global, regional, and personal levels to “keep 1.5 alive.”

What’s the best way to reduce climate impact of food?

Food is a big part of everyone’s carbon footprint, and it’s important to understand the impact of our personal food consumption. Individual food choices can emit as many greenhouse gases as personal electricity use. Plant-based diets generally...

How greenhouse gases and climate change impact the efficiency of photosynthesis

A review in the Journal of Experimental Botany found that higher temperatures reduce the efficiency of enzymes involved in photosynthesis and impair a plant's ability to control water loss and regulate carbon dioxide uptake. While increased carbon dioxide levels are understood to accelerate plant growth by boosting photosynthesis, researchers suggest these effects more than offset the potential gain.

As of 2024, China is the largest overall contributor to global greenhouse gas emissions

Due to its large population, the nation's per capita emissions continue to lag behind those of the US, Canada, Russia, Australia, and Saudi Arabia. The Arab country has experienced the most significant increase in per capita greenhouse gas emissions since 1990, now leading the world at 22.8 metric tons of carbon dioxide equivalent per capita.

Why Earth would become a more deadly environment without the ozone layer

The ozone layer blocks almost all of the sun's harmful, including dangerous UVC rays that can damage cells by breaking chemical bonds. Without it, rates of skin cancer, crop failures, oceanic die-offs, and widespread ecosystem collapse would increase significantly, making Earth largely uninhabitable.

The world's wealthiest 10% are responsible for 48% of greenhouse gas emissions

An analysis by the International Energy Agency found that in 2021, the top 1% of emitters each produced over 50 metric tons of carbon dioxide, over 1,000 times the amount produced by those in the bottom 1%. The average energy-related carbon footprint, including household heating and electricity use, was about 4.7 metric tons per person.

Greenhouse gas concentrations can be measured using spectroscopy

Each type of greenhouse gas absorbs a distinct set of wavelengths of light, which serve as a unique spectral signature. By shining light through an atmospheric sample and measuring the light on the other side, the amount of each gas can be calculated from the amount of missing light.

Global CO2 levels as measured at Hawaii’s Mauna Loa Observatory, managed by the US government’s NOAA.

The Global Monitoring Laboratory conducts research on greenhouse gas and carbon cycle feedbacks, changes in clouds, aerosols, and surface radiation, and recovery of stratospheric ozone.

The greenhouse effect was discovered by analyzing Earth's temperature

Using mathematical techniques developed to analyze heat transfer, Jean-Baptiste Joseph Fourier showed that Earth should be significantly cooler if solar radiation were the only contributor to its surface temperature. By considering that the atmosphere could amplify the sun's warming effect, he formulated what became known as the greenhouse effect.

Why bacterial bioremediation may help counter the negative effects of past chemical solutions

Molecules such as DDT, a synthetic insecticide, and PFAS—"forever" chemicals used to make products resistant to heat, water, and grease—have historically been used across various industries but are now known to be harmful. Microbes that can convert some of these substances into nontoxic products, such as water and carbon dioxide, have already been identified, with ongoing research to find others.

By absorbing 90% of the thermal energy trapped by greenhouse gases, oceans are providing increasingly more energy to power the rapid strengthening of hurricanes.

The food industry's hard-to-solve pollution

One-quarter of the world's greenhouse gas emissions result from food and agriculture. That whopping number includes production and post-farm processes like distribution. See a visualization of the data along with a breakdown explaining how each process contributes to emissions, and why it’s so difficult to improve the agriculture industry.