View when each UN member signed the Montreal Protocol

The history of the Montreal Protocol, the only universally ratified treaty in UN history

Mario Molina and F. Sherwood Rowland discovered that chlorofluorocarbons released chlorine atoms that could break down molecules making up the protective ozone layer. Despite attempts to discredit scientists and economic concerns raised by politicians, the agreement to phase out ozone-depleting substances was signed in 1987.

How the Montreal Protocol supported developing nations in phasing out ozone-depleting substances

Established in 1991, the Multilateral Fund for the Montreal Protocol finances developing nations' transition to cleaner technologies. It has disbursed more than $4B across more than 140 countries and was the first financial mechanism created under an international treaty.

How amendments to the Montreal Protocol have expanded global ozone protections

Since 1990, five major amendments—London, Copenhagen, Montreal, Beijing, and Kigali—have accelerated chemical phase-outs, added new substances, such as hydrochlorofluorocarbons, and tightened enforcement.

The Montreal Protocol helped prevent significant quantities of greenhouse gas emissions

By phasing out ozone-depleting chemicals between 1990 and 2010, the Montreal Protocol prevented emissions equal to 135 gigatons of CO₂—avoiding an estimated 0.5 to 1 degrees Celsius of additional global warming by 2100.

Go inside the global effort that led to the Montreal Protocol in this narrative podcast

Nobel laureate Mario Molina and other key voices recount how science and diplomacy converged to develop a plan to close the ozone hole, offering insight into history's most successful environmental treaty.

Learn why the Montreal Protocol may help prevent millions of cancer deaths

By restoring the ozone layer and reducing ultraviolet exposure, full implementation of the Montreal Protocol is expected to prevent about 443 million cases of skin cancer, 2.3 million skin cancer deaths, and 63 million cases of cataracts among Americans born from 1890 to 2100.

Why a Montreal Protocol amendment cut back on the replacements for CFCs

Hydrofluorocarbons were introduced in the 1990s as ozone-safe substitutes for chlorofluorocarbons and hydrochlorofluorocarbons. However, scientists later found that they trap thousands of times more thermal energy in the atmosphere than carbon dioxide does, prompting a 2016 amendment to the Protocol to phase them out.

A UN-led treaty may establish rules to phase out plastic globally

With support from more than 175 nations, a treaty led by the United Nations is being negotiated to establish enforceable global rules for plastic production and pollution by 2025. Negotiations come as the total amount of plastic in the ocean has increased by 50% from 2017 to 2022.

The ozone layer is on track to recover to pre-1980 levels by mid-century

Thanks to the Montreal Protocol, the ozone layer is steadily recovering and, according to a 2022 assessment, is expected to return to 1980 levels by 2040 globally, 2045 over the Arctic, and 2066 over Antarctica.

How a skin cancerous growth shifted an initially skeptical President Reagan on the ozone crisis

While a 1985 Nature study revealing the Antarctic ozone hole jolted public concern, Reagan's administration was more focused on the Cold War than on environmental policy. His health scare and the market potential for developing alternatives to chlorofluorocarbons helped turn the tide, leading to the Montreal Protocol's unanimous ratification by a bipartisan Senate in 1988.

Hear firsthand how scientists and policymakers saved the ozone layer

In this episode, atmospheric chemist Susan Solomon and Protocol architect Stephen Andersen recount how scientific discovery, diplomacy, and public pressure drove the Montreal Protocol—and share lessons for tackling climate change.

Watch a 1986 television special about the discovery of the ozone hole

The groundbreaking discovery of the Antarctic ozone hole in the mid-1980s marked a critical turning point, galvanizing international action to address the ozone-depleting properties of chlorofluorocarbons, which had been identified about a decade earlier. This environmental crisis was brought vividly to public attention through media pieces like this one.

How a black market for banned refrigerants still threatens ozone recovery and climate progress

Despite the Montreal Protocol's success, illegal trade in chlorofluorocarbons, hydrochlorofluorocarbons, and hydrofluorocarbons persists. Driven by high profits and weak enforcement, smugglers supply banned refrigerants, causing significant ozone depletion and greenhouse gas emissions equivalent to billions of tons of carbon dioxide.

How scientists earned themselves a Nobel Prize by discovering what destroyed ozone

In 1974, chemists Mario Molina and F. Sherwood Rowland showed that chlorofluorocarbons—then used as aerosol propellants, refrigerants, and industrial solvents—rise into the stratosphere and, upon being struck by ultraviolet radiation, release chlorine atoms, which break apart ozone molecules. Their work earned them the Nobel Prize in chemistry in 1995.

The international agreement to address antimicrobial resistance

Antimicrobial resistance has become an increasingly glaring problem for both health and agriculture. In 2024, the United Nations announced a new suite of clear actions and targets that—taken together with existing efforts—can help address superbugs in a meaningful way and on a global scale. This page from the UN lays out these efforts, with links to additional information on the many aspects of the initiative.

When signing the Paris Agreement, almost 200 nations committed to pursuing efforts to limit global warming to 1.5 degrees Celsius above preindustrial levels, based on guidance from the Intergovernmental Panel on Climate Change.

How the Montreal Protocol made CFCs the most valuable Miami contraband after cocaine

Following the 1990s production ban, smugglers flooded Miami with illegal chlorofluorocarbons used in air conditioning. A 15-kilogram cylinder bought for $70 in Europe could sell for $242 in the US, fueling multimillion-dollar black-market trade. (Some users may experience a paywall.)

The Clean Air Act became the cornerstone of modern air pollution control

Passed in 1970 and strengthened through multiple amendments, the Clean Air Act authorizes the EPA to set national air quality standards, regulate industrial and vehicle emissions, and reduce pollutants such as ozone, sulfur dioxide, and lead.

Environmental regulation had bipartisan support in the 1970s

During the 1970s, Democrats and Republicans alike backed landmark environmental laws. Congress passed the Clean Air, Clean Water, and Endangered Species Acts with overwhelming bipartisan majorities—reflecting broad public agreement on protecting the environment.

193 nations are members of the United Nations

The UN's Member States webpage provides an alphabetical list of all 193 member countries, along with the exact dates they were admitted. Take a look at how the UN has expanded over time and understand each nation's place in the global organization.

The United Nations was founded in San Francisco in 1945.

See a visual record of how Roosevelt helped build the United Nations

When President Truman appointed Eleanor Roosevelt to the first US delegation to the UN in 1946, her male colleagues assigned her to a minor committee, assuming she would play a minor role. In the end, she became one of the delegation's most effective negotiators—and chaired the drafting of the Universal Declaration of Human Rights.

Roosevelt chaired more than 3,000 hours of debate to produce the Universal Declaration of Human Rights

Roosevelt led the drafting committee for the Universal Declaration of Human Rights, guiding representatives from 18 nations through debate on conflicting ideas about rights, government, and citizenship. The General Assembly unanimously adopted the final document in December 1948.

Ozone protects against the sun's UV radiation and enhances the greenhouse effect

In the stratosphere, trioxygen molecules can absorb harmful ultraviolet radiation from the sun, preventing it from reaching Earth's surface, where it can harm organisms and raise surface temperatures. In the lower atmosphere, ozone acts as a greenhouse gas, trapping thermal radiation.

The EPA partners with other countries to strengthen environmental protection

Through bilateral programs on every continent, the EPA shares American environmental expertise with developing nations and economies in transition. These partnerships support air and water protection, chemical safety, and pollution control, while advancing US environmental priorities abroad.

A majority in surveyed countries approve of the UN

A 2024 Pew Research Center survey found that a median of 58% across 35 countries viewed the UN favorably, while 31% held unfavorable views. Notably, younger adults tended to view the UN more positively than older generations. The report offers a detailed, country-by-country analysis of global perceptions of the UN.

Fluorinated molecules are the most impactful, longest-lasting greenhouse gases

Developed as replacements for ozone-depleting substances in refrigeration and air conditioning systems, these compounds are released through leaks in and ongoing use of these appliances, as well as from various industrial processes. They can remain in the atmosphere for thousands of years and have warming potentials that are a thousand to tens of thousands of times greater than those of carbon dioxide.

The international trademark framework is called the Madrid Protocol

Trademarks vary from country to country, but an agreement called the Madrid Protocol allows trademark protections across more than 100 participating countries. While the Madrid Protocol expands trademark access, it doesn't necessarily grant blanket protections across the participating countries, meaning each country is still in charge of its own trademark enforcement.

How sunlight helps chlorofluorocarbons destroy the ozone molecules that block solar radiation

CFCs, which are used in old refrigerants, air conditioners, and aerosol sprays, do not react with atmospheric molecules. Once they reach the stratosphere, ultraviolet radiation breaks chlorine atoms off of them, which can each break apart more than 100,000 ozone molecules, thinning Earth's protective layer against ultraviolet radiation.

Learn about the history of the Universal Declaration of Human Rights

The Universal Declaration of Human Rights was adopted by the UN General Assembly in 1948. This video explains the history, purpose, preamble, and all 30 articles of the UDHR, which established a universal human rights standard for people worldwide.

The GATT and its successor, the WTO, were established to lower trade barriers

Signed in 1947, the General Agreement on Tariffs and Trade began systematically reducing tariffs and trade barriers among member nations. In 1995, it was replaced by the World Trade Organization, which expanded those rules and established a formal dispute settlement system.

Why the ozone hole altered Southern Hemisphere jet streams and rainfall patterns

Ozone depletion over Antarctica shifted jet streams southward, drying Australia while increasing rainfall in Uruguay, Brazil, Paraguay, and Argentina. Around the turn of the millennium, these trends began to slow as the Montreal Protocol phased out ozone-depleting substances.

The Clean Water Act became the national standard for protecting American waters

Enacted in 1972, the Clean Water Act grants the Environmental Protection Agency the authority to regulate pollutant discharges, establish water quality standards, and oversee water pollution controls. Its scope has narrowed due to recent Supreme Court rulings.

The 5 permanent Security Council members can veto resolutions

The UN Security Council veto is a power held by its five permanent members—China, France, Russia, the UK, and the US—allowing any one of them to block resolutions, regardless of international consensus. It has been used over 300 times since the UN's founding.

As of 2023, more than 130 nations have enacted bans or restrictions on plastic items, starting with Bangladesh's ban on plastic bags in 2002.

Watch the historic treaty signing that established NATO in 1949

NATO was created with the signing of the North Atlantic Treaty on April 4, 1949, in Washington, DC. The clip embedded in the webpage includes a newsreel with an excerpt from US President Harry Truman’s speech celebrating the historic day.

Earth Day has become the largest civic event in the world

What began in 1970 with 20 million Americans now involves more than 1 billion participants across over 190 countries each year. Earth Day now encompasses rallies, cleanups, and climate actions worldwide.

The Non‑Proliferation Treaty was designed to prevent new states from developing nuclear bombs

The Treaty on the Non‑Proliferation of Nuclear Weapons (created in 1968, effective 1970) binds non-nuclear states to forgo nuclear weapons and commits nuclear powers to share peaceful technology and pursue disarmament—forming the core of the global non-proliferation regime.

Oxygen and ozone molecules absorb up to 99.9% of UV radiation reaching Earth

Although they make up no more than 10 out of every million molecules in the ozone layer, ozone provides outsized protection by absorbing the most energetic wavelengths of ultraviolet radiation. This absorption increases thermal energy in the stratosphere, causing temperatures there to rise with altitude.

During the Cold War and into the 21st century, US and Soviet/Russian leaders repeatedly agreed to arms control treaties, though strained tensions have led to the expiration of agreements in recent years.

Most of the 86,000 consumer chemicals registered with the US EPA have never received rigorous toxicity testing, though not all those are still in current use.

The UN's primary goal is to promote peace and cooperation

The UN's self-proclaimed mission is to promote peace, protect human rights, and tackle global challenges like poverty and climate change. The About Us page on the UN's website is a good entry point to understand how this international organization works and its impact in today's world.

President Harry Truman appointed Roosevelt as one of the first US delegates to the United Nations

After FDR's death in 1945, Roosevelt joined the delegation to the newly established United Nations. She was the only woman among the General Assembly delegates and was unanimously elected to chair the UN Commission on Human Rights.

The 1951 Refugee Convention established international refugee rights and state obligations amid mass World War II displacement

The international treaty defines refugee status and outlines refugees' entitled rights while establishing state obligations to protect them. The UNHCR explains the convention's significance in creating the legal framework governing refugee protection worldwide.

Explore the UN’s interactive guide to global plastic pollution

Around the world, 1 million plastic drinking bottles are purchased every minute, while 500 billion single-use plastic bags are used worldwide every year. In total, half of all plastic produced is designed to be used only once—and then thrown away.

As of 2024, 13 states have plans to phase out gas-powered cars

In 2022, California adopted the Advanced Clean Cars II Act, which requires all new passenger cars, trucks, and SUVs sold to produce zero emissions by 2035. Other states adopted similar laws, joining more than 50 countries with phaseout plans.

Why the Antarctic climate enabled British scientists to discover the ozone hole

In the Antarctic stratosphere, polar conditions facilitate the formation of polar stratospheric clouds, which allow chlorine compounds from chlorofluorocarbons to accumulate. In 1985, British Antarctic Survey scientists detected massive springtime losses over Antarctica, as accumulated compounds destroyed significant amounts of ozone once sunlight returned.

The Office of Air and Radiation oversees America's clean air and climate programs

The office develops and enforces national standards for air quality, vehicle emissions, and radiation protection. In 2025, the EPA announced the closure of two key divisions under the office responsible for regulating climate and air pollution: the Office of Atmospheric Protection and the Office of Air Quality Planning and Standards.

There are 6 primary governing bodies at the UN

The United Nations is structured around six main bodies: the General Assembly, Security Council, Economic and Social Council, Trusteeship Council, International Court of Justice, and Secretariat. Each plays a distinct role in promoting peace, justice, and cooperation worldwide.

The General Agreement on Tariffs and Trade and its successor, the WTO, was formed to reduce trade barriers between nations.